The effect of edge topological dislocations on the phase matching spectrum of quadratic nonlinear photonic crystals was studied theoretically and experimentally. We have found that the parity of the dislocation's topological charge governs the transfer of energy between an input wave and its second harmonic. A dislocation with an odd topological charge nulls the efficiency of the otherwise optimal phase matched wavelength, whereas high conversion is now achieved at new wavelengths that exhibited low efficiency without the dislocation. However, when the topological charge is an even number, the dislocation has a negligible effect on the efficiency curve. This effect is observed in periodically poled crystals having a single peak in the phase matching spectrum, as well as in phase-reversed and quasiperiodic nonlinear photonic crystals that are characterized by multiple efficiency peaks, where a dimple is imprinted on each spectral peak.
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http://dx.doi.org/10.1103/PhysRevLett.112.053901 | DOI Listing |
Inorg Chem
December 2024
Department of Chemistry, National Institute of Technology, Rourkela 769008, Odisha, India.
Design of hierarchical hollow nanoheterostructure materials through interfacial and defect engineering is an innovative approach for achieving optimal charge separation dynamics and photon harvesting efficiency. Herein, we have described a facile technique to fabricate hollow MOF-derived C, N-doped-CoO (C, N-CoO) dodecahedral particles enwrapped with MgInS nanosheets for enhanced N reduction performance. ZIF-67 was initially used as a sacrificial template to prepare hollow C, N-CoO using a carbonization route followed by low-temperature calcination treatment.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
School of Materials Science and Engineering, UNSW Sydney, NSW 2052, Australia.
Domain walls are quasi-one-dimensional topological defects in ferroic materials, which can harbor emergent functionalities. In the case of ferroelectric domain wall (FEDW) devices, an exciting frontier has emerged: memristor-based information storage and processing approaches. Memristor solid-state FEDW devices presented thus far, however predominantly utilize a complex network of domain walls to achieve the desired regulation of density and charge state.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Institute for Advanced Study, Tsinghua University, Beijing 100084, China.
The nonintegrable higher spin Kitaev honeycomb model has an exact Z_{2} gauge structure, which exclusively identifies quantum spin liquid in the half-integer spin Kitaev model. But its constraints for the integer-spin Kitaev model are much limited, and even trivially gapped insulators cannot be excluded. The physical implications of exact Z_{2} gauge structure, especially Z_{2} fluxes, in integer-spin models remain largely unexplored.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
We show that a non-Hermitian lattice with a disclination can host topological disclination states that are induced by on-site gain and loss. The disclination states are inherently non-Hermitian as they do not exist in the limit of zero gain or loss. They arise from charge fractionalization in the non-Hermitian lattice, which we establish using non-Hermitian Wilson loops calculated with biorthogonal products.
View Article and Find Full Text PDFPNAS Nexus
December 2024
Department of Mechanical and Energy Engineering, Southern University of Science and Technology, Shenzhen 518055, China.
Ferroelectric nematic (N) liquid crystals present a compelling platform for exploring topological defects in polar fields, while their structural properties can be significantly altered by ionic doping. In this study, we demonstrate that doping the ferroelectric nematic material RM734 with cationic polymers enables the formation of polymeric micelles that connect pairs of half-integer topological defects. Polarizing optical microscopy reveals that these string defects exhibit butterfly textures, featured with a 2D polarization field divided by Néel-type kink walls into domains exhibiting either uniform polarization or negative splay and bend deformations.
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