Competition between sp³-C-N vs sp³-C-F reductive elimination from Pd(IV) complexes.

J Am Chem Soc

Department of Chemistry, University of Michigan , 930 North University Avenue, Ann Arbor, Michigan 48109, United States.

Published: March 2014

This communication describes the design of a model system that allows direct investigation of competing sp(3)-C-N and sp(3)-C-F bond-forming reductive elimination from a Pd(IV) fluoro sulfonamide complex. The reductive elimination selectivity varies dramatically as a function of reaction additives. A mechanism is proposed that provides a rationale for these effects.

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http://dx.doi.org/10.1021/ja411433fDOI Listing

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