A novel TPE-based expanded oxacalixarene with typical aggregation-induced emission properties was synthesized by the SNAr reaction of dihydroxytetraphenylethylene with 2,6-dichloropyrazine. The conformation of the oxacalixarene is adjusted by the encapsulated guests (benzene or THF), which results in different supramolecular grid structures in the solid state.
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| http://dx.doi.org/10.1021/jo402884a | DOI Listing |
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