A novel and highly efficient Pd(0)-catalyzed domino reaction to prepare cyclopropane derivatives has been established. The process involves a Heck-type coupling reaction and a C(sp(3))-H bond activation. Preliminary DFT calculations suggest that a four-membered palladacycle intermediate is involved.
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| http://dx.doi.org/10.1039/c3cc49231a | DOI Listing |
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