Ultrafiltration membrane processes have become an established technology in the treatment and reuse of secondary effluents. Nevertheless, membrane fouling arises as a major obstacle in the efficient operation of these systems. In the current study, the performance of tubular ultrafiltration ceramic membranes was evaluated according to the roles exerted by membrane pore size, transmembrane pressure and feed concentration on a binary foulant system simulating textile wastewater. For that purpose, carboxymethyl cellulose sodium salt (CMC) and an azo dye were used as colloidal and organic foulants, respectively. Results showed that a larger pore size enabled more solutes to get adsorbed into the pores, producing a sharp permeate flux decline attributed to the rapid pore blockage. Besides, an increase in CMC concentration enhanced severe fouling in the case of the tighter membrane. Concerning separation efficiency, organic matter was almost completely removed with removal efficiency above 98.5%. Regarding the dye, 93% of rejection was achieved. Comparable removal efficiencies were attributed to the dynamic membrane formed by the cake layer, which governed process performance in terms of rejection and selectivity. As a result, none of the evaluated parameters showed significant influence on separation efficiency, supporting the significant role of cake layer on filtration process.
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http://dx.doi.org/10.1016/j.watres.2014.01.064 | DOI Listing |
RSC Adv
January 2025
a, Department of Chemical Engineering, Birla Institute of Technology & Science, Pilani Campus Pilani Rajasthan 333031 India +91-1596255839.
To address the limitations of polymeric membranes, mixed matrix membranes for CO separation from biogas mixtures (CO and CH) have been investigated utilizing various fillers. In this study, we investigated novel MMMs using 3D and 2D indium-based MOFs, MIL-68(In)-NH and In(aip), in a polysulfone polymer matrix. To confirm synthesis, both fillers were subjected to XRD and FTIR analysis, as well as FESEM characterization to assess their 2D and 3D structures.
View Article and Find Full Text PDFEnviron Res
January 2025
Key Laboratory of Regional Environment and Eco-restoration, Ministry of Education, Shenyang University, Shenyang, 110044, Liaoning, China. Electronic address:
Nano-microplastics and 17β-E2 have been frequently detected as emerging high-concern pollutants in aquatic systems, and their interaction at the solid/liquid interface has become a research focus in environmental studies. The interfacial sorption kinetics and equilibrium characteristics of 17β-estradiol (17β-E2) on nano-polystyrene (Nano-PS) with different particle sizes and organic functional group modifications were systematically investigated in aqueous environments in this study. The interfacial interaction mechanism between Nano-PS particles and 17β-E2 was elucidated by utilizing SEM, FTIR, XPS and BET techniques.
View Article and Find Full Text PDFLangmuir
January 2025
Ningbo Key Lab of Polymer Materials, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, 315211 Ningbo, P. R. China.
Solar-driven desalination technology is currently an important way to obtain freshwater resources. Significantly, porous materials are used as substrate materials of interface solar evaporator, and their specific impact of water transport property and thermal management during evaporation is worth exploring. In this paper, poly(vinyl alcohol) (PVA) sponges were prepared by a chemical foaming method, adjusted the PVA polymerization degree, and formaldehyde-hydroxyl ratio to regulate the pore size, and polypyrrole (PPy) was grown in situ on the surface skeleton of PVA sponge to construct a new interfacial solar evaporator (PPy/PVA) with different pore structures.
View Article and Find Full Text PDFAnal Chem
January 2025
Chemistry Department, Indiana University, Bloomington, Indiana 47405, United States.
Charge detection mass spectrometry (CD-MS) is an emerging single-particle technique where both the / and charge are measured individually to determine each ion's mass. It is particularly well-suited for analyzing high mass and heterogeneous samples. With conventional MS, the loss of charge state resolution with high mass samples has hindered the direct coupling of MS to separation techniques like size exclusion chromatography (SEC) and forced the use of lower resolution detectors.
View Article and Find Full Text PDFAnal Chem
January 2025
Institute of Analytical Chemistry, Chemo- and Biosensors, University of Regensburg, Universitaetsstr. 31, Regensburg 93053, Germany.
To ensure high quality of food and water, the identification of traces of pathogens is mandatory. Rapid nucleic acid-based tests shorten traditional detection times while maintaining low detection limits. Challenging is the loss of nucleic acids during necessary purification processes, since elution off solid surfaces is not efficient.
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