We discuss the optimization of photonic crystal waveguides for four-wave mixing (FWM) applications, taking into account linear loss and free-carrier effects. Suitable figures of merit are introduced in order to guide us through the choice of practical, high-efficiency designs requiring relatively low pump power and small waveguide length. In order to realistically perform the waveguide optimization process, we propose and validate an approximate expression for the FWM efficiency, which significantly alleviates our numerical calculations. Promising waveguide designs are identified by means of an exhaustive search, altering some structural parameters. Our approach aims to optimize the waveguides for nonlinear signal-processing applications based on the FWM.
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http://dx.doi.org/10.1364/OL.39.000884 | DOI Listing |
Sci Rep
January 2025
Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh, 11671, Saudi Arabia.
We report the fabrication and characterization of a Bi(III) oxide/polypyrrole (BiO/Ppy) nanocomposite thin film optoelectronic photodetector synthesized by a simple one-pot method. The nanocomposite consists of spherical BiO nanoparticles embedded in a Ppy matrix, forming a porous structure with a high surface area. The XRD analysis reveals that the BiO nanoparticles have a poly-crystalline nature with a crystal size of 40 nm and an optical bandgap of 2.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
Department of Chemistry and Centre for Radiochemistry Research, The University of Manchester, Oxford Road, Manchester M13 9PL, U.K.
Although two examples of σ-bonded -bent [RSbSbR] (R = bulky organo- or Ga-groups) that formally contain the Sb radical trianion moiety are known in p-block chemistry, d- or f-element Sb radical trianion complexes, with or without R-substituents, have remained elusive. Here, we report that reduction of a 77:23 mix of [{Th(Tren)}(μ-η:η-Sb)] (, Tren = {N(CHCHNSiPr)}):[{Th(Tren)}(μ-SbH)] () with 1.5 equiv of KC in the presence of 1.
View Article and Find Full Text PDFACS Nano
January 2025
Department of Mechanical Engineering, University of California at Riverside, Riverside, California 92521, United States.
Sensing light's polarization and wavefront direction enables surface curvature assessment, material identification, shadow differentiation, and improved image quality in turbid environments. Traditional polarization cameras utilize multiple sensor measurements per pixel and polarization-filtering optics, which result in reduced image resolution. We propose a nanophotonic pipeline that enables compressive sensing and reduces the sampling requirements with a low-refractive-index, self-assembled optical encoder.
View Article and Find Full Text PDFNanoscale
January 2025
Physical Chemistry, TU Dresden, Zellescher Weg 19, 01069 Dresden, Germany.
Tunable optical properties exhibited by semiconductor nanocrystals (NCs) in the near infrared (NIR) spectral region are of particular interest in various applications, such as telecommunications, bioimaging, photodetection, photovoltaics, . While lead and mercury chalcogenide NCs do exhibit exemplary optical properties in the NIR, Cu-In-Se (CISe)-based NCs are a suitable environment-friendly alternative to these toxic materials. Several reports of NIR-emitting (quasi)spherical CISe NCs have been published, but their more complex-shaped counterparts remain rather less explored.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Physics, Chemistry and Biology (IFM), Linköping University, Linköping, Sweden.
One of the key advantages of perovskite light-emitting diodes (PeLEDs) is their potential to achieve high performance at much higher current densities compared to conventional solution-processed emitters. However, state-of-the-art PeLEDs have not yet reached this potential, often suffering from severe current-efficiency roll-off under intensive electrical excitations. Here, we demonstrate bright PeLEDs, with a peak radiance of 2409 W sr m and negligible current-efficiency roll-off, maintaining high external quantum efficiency over 20% even at current densities as high as 2270 mA cm.
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