An original synthesis of chiral benzofulvenes triggered by organocopper reagents is reported. These enantiopure products are available through a highly chemo-, regio-, diastereo-, and enantioselective bis(alkylating) cycloisomerization process. A double chirality transfer (central-to-axial-to-central) is observed.
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Double transfer of chirality in organocopper-mediated bis(alkylating) cycloisomerization of enediynes.
Angew Chem Int Ed Engl
March 2014
Aix-Marseille Université, CNRS, Institut de Chimie Radicalaire UMR7273, 13390 Marseille (France).
An original synthesis of chiral benzofulvenes triggered by organocopper reagents is reported. These enantiopure products are available through a highly chemo-, regio-, diastereo-, and enantioselective bis(alkylating) cycloisomerization process. A double chirality transfer (central-to-axial-to-central) is observed.
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