AI Article Synopsis
- A new method for ortho-C-H borylation of aromatic aldimines from pentafluoroaniline was developed using an iridium catalyst.
- The reaction occurs at a temperature of 120 °C and produces borylated products with high efficiency.
- The iridium complex is created in the reaction mixture from specific precursors and works alongside 2-norbornene to achieve good regioselectivity.
Article Abstract
The development of an Ir-catalyzed ortho-C-H borylation of aromatic aldimines derived from pentafluoroaniline is reported. This reaction proceeded at 120 °C to afford the corresponding borylated products in high yield with good regioselectivity using an Ir complex formed in situ from [Ir(OMe)(cod)]2/2(C6F5)3P in the presence of 2-norbornene.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/c3ob42497a | DOI Listing |
Publication Analysis
Top Keywords
ortho-c-h borylation
8
borylation aromatic
8
aromatic aldimines
8
aldimines derived
8
derived pentafluoroaniline
8
iridium-catalyzed ortho-c-h
4
pentafluoroaniline bispinacolatediboron
4
bispinacolatediboron development
4
development ir-catalyzed
4
ir-catalyzed ortho-c-h
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!