The title compound, C18H21BF2N2, is a lipophilic dye based on a BODIPY fluoro-phore backbone, which was developed for microscopic imaging of lipid droplets; the mol-ecule has a planar BODIPY core [dihedral angle between the pyrrole rings = 2.3 (3)°] and two tetra-methyl-ene substituents at the 2,3- and 5,6-positions in a half-chair conformation. One of the tetra-methyl-ene substituents is disordered over two two sets of sites with site occupancies of 0.5. In the crystal, pairs of C-H⋯F inter-actions link the mol-ecules into inversion dimers. Neighbouring dimers are linked by further C-H⋯F inter-actions, forming an infinite array. C-H⋯π and π-π [centroid-centroid distance = 4.360 (3) Å] inter-actions are observed between the BODIPY core and the tetra-methyl-ene substituents of neighbouring dimer pairs.
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http://dx.doi.org/10.1107/S1600536813033448 | DOI Listing |
Acta Crystallogr Sect E Struct Rep Online
January 2014
Department of Chemistry, Nanoscience Center, University of Jyväskylä, PO Box 35, FIN-40014 University of Jyväskylä, Finland.
The title compound, C18H21BF2N2, is a lipophilic dye based on a BODIPY fluoro-phore backbone, which was developed for microscopic imaging of lipid droplets; the mol-ecule has a planar BODIPY core [dihedral angle between the pyrrole rings = 2.3 (3)°] and two tetra-methyl-ene substituents at the 2,3- and 5,6-positions in a half-chair conformation. One of the tetra-methyl-ene substituents is disordered over two two sets of sites with site occupancies of 0.
View Article and Find Full Text PDFActa Crystallogr Sect E Struct Rep Online
August 2008
Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280, Japan.
The title compound, C(18)H(16)O(2), was prepared by reduction of 2-(5,6,7,8-tetra-hydro-2-naphtho-yl)benzoic acid with zinc dust. The benzene ring in the tetra-hydro-naphthyl substituent is nearly perpendicular to the plane of the isobenzofuran-1(3H)-one ring [87.15 (4)°].
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