A photofuel cell comprising two photocatalysts TiO2 and Ag-TiO2 is demonstrated. The open circuit voltage, short circuit current, and maximum electric power of the PFC were 1.59 V, 74 μA, and 14 μW, respectively. The electron flow was rectified due to the Schottky barrier between TiO2 and Ag nanoparticles.
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http://dx.doi.org/10.1039/c4cc00194j | DOI Listing |
Chemphyschem
December 2024
Institutes of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi, 464-8603, Japan.
Formic acid (HCOOH) has attracted much attention as a promising power source for portable electronic devices because of its ease of storage and transportation. Here we report that a simple HCOOH photo-fuel cell (PFC) consisting of mesoporous anatase TiO photoanode and Pt cathode stably delivers a short-circuit photocurrent (J) of 5.94 mA cm and an open-circuit voltage of 0.
View Article and Find Full Text PDFTalanta
July 2024
Key Laboratory of Modern Agricultural Equipment and Technology (Jiangsu University), Ministry of Education, School of Agricultural Engineering, Jiangsu University, Zhenjiang, 212013, PR China; School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, PR China. Electronic address:
The detection of transmissible gastroenteritis virus (TGEV) is of great significance to reduce the loss of pig industry. A LAMP-visualization/PFC self-powered dual-mode output sensor platform was constructed to detect TGEV by combining a simple and intuitive photoelectrochromic material with a highly sensitive PFC self-powered sensing platform without external power supply. The PFC sensing substrate was constructed using CdS nanoparticles modified ZnO NRs (CdS/ZnO NRs) as the photoanode, which exhibited high photoactivity, and Prussian blue (PB) as the cathode.
View Article and Find Full Text PDFAnal Chim Acta
April 2024
Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), Hubei Key Laboratory of Bioinorganic Chemistry & Materia Medica, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan, 430074, China. Electronic address:
Self-powered electrochemical sensors based on photofuel cells have attracted considerable research interest because their unique advantage of not requiring an external electric source, but their application in portable and multiplexed targets assay is limited by the inherent mechanism. In this work, a portable self-powered sensor constructed with multichannel photofuel cells was developed for the ratiometric detection of mycotoxins, namely ochratoxin A (OTA) and patulin (PAT). The spatially resolved CdS/BiS-modified photoanodes and a shared Prussian Blue cathode were integrated on an etched indium-tin oxide slide to fabricate the multichannel photofuel cell.
View Article and Find Full Text PDFAnal Chem
February 2024
Key Laboratory of Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, P. R. China.
A self-powered photoelectrochemical (PEC) sensor has attracted widespread attention in the field of analysis, but it is still a challenge to enhance its response signals with rational strategies. In this work, a novel self-powered PEC sensing platform was developed for the quantitative detection of gatifloxacin (GAT) based on a photofuel cell consisting of two types of ZIF-derived ZnO/CoO heterojunctions as photoactive materials. Peroxymonosulfate (PMS) was first used as an electron acceptor coupled with a photofuel cell to develop a synergetic signal amplification strategy.
View Article and Find Full Text PDFDalton Trans
October 2023
Institutes of Innovation for Future Society, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan.
Hydrogen peroxide (HO) possesses both strong oxidizing and moderate reducing ability. Due to the unique chemical reactivity, one-compartmentalization of fuel cells is possible by using HO as both the fuel and oxidant for fuel cells (HO-FC). To enhance the anode reaction (HO → O + 2H + 2e) of the HO-FC, a noble metal-free HO-photo fuel cell (PFC) has been newly developed for enhancing the conversion from chemical energy to electric energy with only emission of water and oxygen.
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