The innovative properties of nanomaterials make them suitable for various applications in many fields. In particular, TiO2 nanoparticles (nTiO2) are widely used in paints, in cosmetics and in sunscreens that are products accessible to the mass market. Despite the great increase in the use of such nanomaterials, there is a paucity of general information about their potential effects to the aquatic species, especially to saltwater ones. Moreover, the difficulties of determining the effective exposure scenario make the acquired information low comparable. In this work, questions about the complexity of the real exposure scenario determination are discussed. The state of the art, concerning the experimental activities with nTiO2 toward the saltwater organisms is firstly illustrated, providing statistical information about the different matrices, organisms and nanoparticles employed. A comparison of the nTiO2 ecotoxicity effects, grouped by taxonomic classes, is provided illustrating their relative experimental conditions. Findings show the need to develop specific protocols for toxicity tests with ENPs to control the variability of experimental conditions. Some advices are finally proposed for the future experimental activities.
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http://dx.doi.org/10.1016/j.envint.2014.01.012 | DOI Listing |
Langmuir
January 2025
Chemistry and Structure of novel Materials, University of Siegen, Paul-Bonatz Strasse 9-11, 57068 Siegen, Germany.
The surface charge of metal oxides is an important property that significantly contributes to a wide range of phenomena, including adsorption, catalysis, and material science. The surface charge can be predicted by determining the isoelectric point (IEP) of a material and the pH of a solution. Although there have been several studies of the IEP of metal oxide (nano)particles, only a few have reported the IEP of metal oxide films.
View Article and Find Full Text PDFNanoscale
January 2025
Department of Molecular Science, BioCenter, Swedish University of Agricultural Sciences, Box 7015, 75007 Uppsala, Sweden.
The recent COVID-19 pandemic has set a strong quest for advanced understanding of possible tracks in abating and eliminating viral infections. In the view that several families of "pristine" small oxide nanoparticles (NPs) have demonstrated viricidal activity against SARS-CoV-2, we studied the effect of two NPs, with presumably different reactivity, on two viruses aiming to evaluate two "primary suspect" routes of their antiviral activity, either specific blocking of surface proteins or causing membrane disruption. The chosen NPs were non-photoactive 3.
View Article and Find Full Text PDFRSC Adv
January 2025
Institute of Fundamental Physics (AbinitSim Unit, ABINITFOT Group), Consejo Superior de Investigaciones Científicas (CSIC) E-28006 Madrid Spain
The unique structural properties of zeolites make them ideal environments for encapsulating subnanometric metal clusters on their microporous channels and cavities, showing an enhanced catalytic performance. As a first step towards the functionalization of these clusters as photocatalysts as well, this work addresses the optical properties of zeolite-encapsulated Cu-TiO nanoparticles as well as their application in the photo-induced activation of CO by sunlight. Model density functional theory (DFT) calculations indicate the stability of the Cu cluster adsorbed on the TiO nanoparticles filling the pores of a model zeolite structure.
View Article and Find Full Text PDFAquat Toxicol
January 2025
International Research Center for Marine Biosciences at Shanghai Ocean University, Ministry of Science and Technology, Shanghai Ocean University, Shanghai 201306, PR China. Electronic address:
Perfluorooctanoic acid (PFOA) and nano-titanium dioxide (nano-TiO₂) are widely used in industrial applications such as manufacturing and textiles, and can be released into the environment, causing toxicity to marine organisms. To study the effects of these pollutants on the gonadal development, we exposed the males of Mytilus coruscus to varying PFOA concentrations (2 and 200 μg/L) alone or combined with nano-TiO (0.1 mg/L, size: 25 nm) for 14 days.
View Article and Find Full Text PDFChem Sci
January 2025
Applied Chemistry and Environmental Science, School of Science, STEM College, RMIT University Melbourne Victoria 3000 Australia
High-temperature reduction of TiO causes the gradual formation of structural defects, leading to oxygen vacancy planar defects and giving rise to Magnéli phases, which are substoichiometric titanium oxides that follow the formula Ti O, with 4 ≤ ≤ 9. A high concentration of defects provides several possible configurations for Ti and Ti within the crystal, with the variation in charge ordered states changing the electronic structure of the material. The changes in crystal and electronic structures of Magnéli phases introduce unique properties absent in TiO, facilitating their diverse applications.
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