The coordination polymer poly[[aqua(μ-oxalato)[1H-1,2,4-triazole-5(4H)-thione]cadmium(II)] monohydrate].

Acta Crystallogr C Struct Chem

College of Life Science, Fujian Agriculture and Forestry University, Fuzhou, Fujian 350002, People's Republic of China.

Published: February 2014

The title complex, {[Cd(C2O4)(C2H3N3S)(H2O)]·H2O}n, has a two-dimensional metal-organic framework, with the Cd(II) cation coordinated by three oxalate ligands, a 1H-1,2,4-triazole-5(4H)-thione (H2trzS) ligand and a water molecule. The CdO6S and oxalate units form an extended two-dimensional layered structure, with the terminal H2trzS ligands bonded to the Cd(II) sites through the thione S atoms. Hydrogen-bond interactions exist between adjacent layers.

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http://dx.doi.org/10.1107/S2053229614000102DOI Listing

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