Autonomous bubble-propelled catalytic micro- and nanomachines show great promise in the fields of biomedicine, environmental science, and natural resources. It is envisioned that thousands and millions of such micromachines will swarm and communicate with each other, performing desired actions. To date, mainly platinum catalyst surfaces have been used for the decomposition of a fuel, hydrogen peroxide, to oxygen bubbles. Here we propose Pt-free, low-cost inorganic catalysts for powering micromotors based on silver and manganese dioxide surfaces. Such Ag- and MnO2-based bubble-powered micromotors show fast motion even at very low concentrations of fuel, down to 0.1% of H2O2. These catalysts should enable unparalleled widespread use of such motors in real applications, as it will be possible to make them in large quantities at low cost.
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http://dx.doi.org/10.1021/ja411705d | DOI Listing |
J Colloid Interface Sci
December 2024
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, PR China. Electronic address:
Contemporary industrial production and human activity release numerous toxins into our environment. Metal-organic frameworks (MOFs) are potential candidates for addressing these toxins due to their ultrahigh surface area, tailored pore size, and responsiveness to stimuli. With the rise of micro/nanomotor, imparting active motion to MOFs becomes crucial for efficiently performing tasks in challenging locations.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Key Laboratory of Quantum Materials and Devices of Ministry of Education, School of Physics, Southeast University, Nanjing 211189, China.
This Letter introduces MXene-based rod-like micromotors, consisting of assembled FeO@TiC core-shell nanospheres, that leverage external magnetic fields for active molecular enrichment and selective surface-enhanced Raman scattering (SERS) sensing. These micromotors enhance SERS performance by concentrating target molecules directly onto MXene surfaces during movement, enabling rapid and precise detection. Our investigation reveals how these micromotors optimize SERS through effective molecular manipulation and explores the selective Raman enhancement facilitated by the MXene-based platforms, demonstrating their significant potential in analytical applications.
View Article and Find Full Text PDFSmall Methods
November 2024
Department of Chemistry, The University of Hong Kong, Hong Kong, 999077, China.
Synthetic Janus micro/nanomotors can efficiently convert ambient energy into asymmetrical self-propulsive force, overcoming random thermal fluctuations and enabling autonomous migration. Further modifications to the motors can equip them with different functional modules to meet different needs. However, developing a versatile and high-yield fabrication method for multifunctional Janus micromotors remains challenging.
View Article and Find Full Text PDFNanoscale
December 2024
Department of Physics, IIT Bhilai, Kutelabhata, Durg, Chhattisgarh, 491001, India.
Micromotors are the backbone of material research as they are small-sized, self-propelled, intelligent systems capable of performing multiple tasks ranging from biomedicine to environmental monitoring. One of the primary obstacles the field faces is the live detection and differentiation of individual units through a complex environment. In this study, we demonstrate a facile approach for designing light-activated dye-tagged micromotors on a large scale.
View Article and Find Full Text PDFACS Appl Bio Mater
November 2024
Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan.
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