Extending the well-known Thomas-Fermi Z-scaling laws to the Coulomb coupling parameter, we investigate the stabilization of the ionic coupling in isochoric heating [Clérouin et al., Phys. Rev. E 87, 061101 (2013)]. This stabilization is restricted to a domain in atomic number Z, temperature, and density, including strong limitations on high couplings, that can only be obtained for high-Z elements. Contact is made with recent isochoric heating experiments. The consequences for corresponding states with respect to ionic coupling are also quantified via orbital free molecular dynamics simulations. This opens avenues for future isochoric heating experiments.
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http://dx.doi.org/10.1103/PhysRevE.88.063106 | DOI Listing |
J Chem Phys
June 2024
Department of Physics, AlbaNova University Center, Stockholm University, SE-10691 Stockholm, Sweden.
Here, we investigate the hypothesis that despite the existence of at least two high-density amorphous ices, only one high-density liquid state exists in water. We prepared a very-high-density amorphous ice (VHDA) sample and rapidly increased its temperature to around 205 ± 10 K using laser-induced isochoric heating. This temperature falls within the so-called "no-man's land" well above the glass-liquid transition, wherein the IR laser pulse creates a metastable liquid state.
View Article and Find Full Text PDFFoods
June 2024
Department of Energy and Process Engineering, Faculty of Engineering Science and Technology, Norwegian University of Science and Technology, 7034 Trondheim, Norway.
The present article responds to the food engineering community's growing interest in an emerging and lauded approach to food preservation, popularised by its developers as ''. A strong campaign in the scientific literature and mass media has recently promoted this technique as a universal replacement for traditional food freezing and the frozen supply chain by highlighting a number of alleged advantages of ''. Some of these claims therefore require a more neutral and critical assessment against the background of the today's state of the art in food freezing technologies.
View Article and Find Full Text PDFThe combination of isochoric heating of solids by free-electron lasers (FELs) and in situ diagnostics by X-ray Thomson scattering (XRTS) allows for measurements of material properties at warm dense matter (WDM) conditions relevant for astrophysics, inertial confinement fusion, and materials science. In the case of metals, the FEL beam pumps energy directly into electrons with the lattice structure of ions being nearly unaffected. This leads to a unique transient state that gives rise to a set of interesting physical effects, which can serve as a reliable testing platform for WDM theories.
View Article and Find Full Text PDFData Brief
April 2024
Gubkin University, Department of Physical and Colloid Chemistry, 65, Leninsky prospekt, Building 1, 119991 Moscow, Russian Federation.
In order to systematically study the synergistic effect of gas hydrate inhibition with mixtures of methanol (MeOH) and magnesium chloride (MgCl), the impact of these compounds on the thermodynamic stability of methane hydrate in the systems of CH-MeOH-HO, CH-MgCl-HO, and CH-MeOH-MgCl-HO was experimentally investigated. The pressure and temperature conditions of the three-phase vapor-aqueous solution-gas hydrate equilibrium were determined for these systems. The resulting dataset has 164 equilibrium points within the range of 234-289 K and 3-13 MPa.
View Article and Find Full Text PDFPhys Rev E
October 2023
Department of Astrophysical Sciences and Princeton University, Princeton, New Jersey 08540, USA.
The fast ignition paradigm for inertial fusion offers increased gain and tolerance of asymmetry by compressing fuel at low entropy and then quickly igniting a small region. Because this hot spot rapidly disassembles, the ions must be heated to ignition temperature as quickly as possible, but most ignitor designs directly heat electrons. A constant-power ignitor pulse, which is generally assumed, is suboptimal for coupling energy from electrons to ions.
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