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A silver bite: crystalline heterometallic architectures based on Ag-π interactions with a bis-dipyrrin zinc helicate. | LitMetric

A silver bite: crystalline heterometallic architectures based on Ag-π interactions with a bis-dipyrrin zinc helicate.

Chemistry

Laboratoire de Tectonique Moléculaire, UMR UdS-CNRS 7140 icFRC, Institut Le Bel, Université de Strasbourg, 4 rue Blaise Pascal, CS 90032, 67081 Strasbourg cedex (France), Fax: (+33) 3-68-85-13-25.

Published: February 2014

AI Article Synopsis

Article Abstract

An unprecedented mode of assembly of helical motives and Ag(I)  ions in the crystalline state is described. The combination of a Zn(II) helicate based on a 2,2'-bisdpm bearing peripheral benzonitrile moieties with AgX salts, leads to the formation of a tetranuclear core containing Ag-π interactions. Depending on the coordinating ability of the X(-) anion and the solvents used, the tetranuclear complex self-assembles into coordination polymers of varying dimensionality. From the sequence of coordination events (Ag-π or Ag-peripheral site), one may envisage two possible construction scenarios. However, the Ag-π as primary event seems reasonable owing to the rather weak binding propensity of the nitrile group and the chelating nature of the π-clefts.

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Source
http://dx.doi.org/10.1002/chem.201304319DOI Listing

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