The first total synthesis of pandamarilactone-1, an alkaloid of Pandanus amaryllifolius, is reported. The nine-step synthesis features furan oxidation with singlet oxygen and then spiro-N,O-acetalization and elimination to generate the natural product and further Pandanus alkaloids, pandamarilactonines A-D.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3971736 | PMC |
| http://dx.doi.org/10.1021/ol4036424 | DOI Listing |
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