Accessing near-infrared-absorbing BF2-azadipyrromethenes via a push-pull effect.

J Org Chem

Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, School of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China.

Published: February 2014

Novel aza-BODIPYs with significant bathochromic shifts were designed and synthesized by installation of strong electron-withdrawing groups on the para-positions of 1,7-phenyls and electron-donating groups on the para-positions of 3,4-phenyls. These dyes show strong NIR fluorescence emissions up to 756 nm, and absorptions up to 720 nm.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4415601PMC
http://dx.doi.org/10.1021/jo402160bDOI Listing

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