A clue to understand wetting hysteresis on superhydrophobic surfaces is the relation between receding contact angle and surface textures. When the surface textures are large, there is a significant distribution of local contact angles around the drop. As seen from the cross section, the apparent contact angle oscillates as the triple line recedes. Our experiments demonstrate that the origin of these oscillations is a finite size effect. Combining side and bottom views of the drop, we take into account the 3D conformation of the surface near the edge to evaluate an intrinsic contact angle from the oscillations of the apparent contact angle. We find that for drops receding on axisymmetric textures the intrinsic receding contact angle is the minimum value of the oscillation while for a square lattice it is the maximum.
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http://dx.doi.org/10.1021/la403744b | DOI Listing |
Sci Rep
December 2024
Gansu Provincial Ecological Environment Engineering Assessment Center, Lanzhou, 730000, People's Republic of China.
In this study, polyethylene glycol (PEG) and dextran (Dex) were chemically modified to obtain amino-functionalized PEG (PEG-(NH)) and oxidized dextran (ODex). They were subsequently reacted via -NH and -CHO groups to synthesize a macromolecular Schiff base particle. The structures, morphologies, and thermal properties of the macromolecular Schiff base particle were characterized using Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), and thermogravimetry analysis (TGA).
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December 2024
School of Mechanical Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan, 250353, China.
Microtextured microneedles are tiny needle-like structures with micron-scale microtextures, and the drugs stored in the microtextures can be released after entering the skin to achieve the effect of precise drug delivery. In this study, the skin substitution model of Ogden's hyperelastic model and the microneedle array and microtexture models with different geometrical parameters were selected to simulate and analyse the flow of the microtexture microneedle arrays penetrating the skin by the finite-element method, and the length of the microneedles was determined to be 200 μm, the width 160 μm, and the value of the gaps was determined to be 420 μm. A four-pronged cone was chosen as the shape of microneedles, and a rectangle was chosen as the shape of the drug-carrying microneedle.
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December 2024
Faculté des Sciences et Technologies, LEMTA - Université de Lorraine - CNRS UMR 7563, Boîte Postale 70239, Vandoeuvre les Nancy cedex, 54506, France.
The wetting characteristics of fluids play a crucial role in various fields of interface and surface science. Contact angle serves as a fundamental indicator of wetting behavior. However, accurate quantification of wetting phenomena even at the macroscale often poses challenges, particularly due to the hysteresis between receding and advancing contact angles.
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December 2024
Department of Biophysics, Faculty of Environmental Biology, University of Life Sciences in Lublin, Akademicka 13, Lublin, 20-950, Poland.
Physical and photophysical properties of starch-based biopolymer films containing 5-(4-nitrophenyl)-1,3,4-thiadiazol-2-amine (NTA) powder as a nanofiller were examined using atomic force microscopy (AFM), Fourier-transform infrared spectroscopy (FTIR), stationary UV-Vis and fluorescence spectroscopy as well as resonance light scattering (RLS) and time-resolved measurements, and where possible, analyzed with reference to pristine NTA solutions. AFM studies revealed that the addition of NTA into the starch biopolymer did not significantly affect surface roughness, with all examined films displaying similar Sq values ranging from 70.7 nm to 79.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Yunnan Key Laboratory of Wood Adhesives and Glue Products, Southwest Forestry University, Kunming 650224, PR China; College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, PR China. Electronic address:
The manufacturing of soy-based adhesives with high bonding strength, excellent water resistance, and exceptional environmental performance still faces difficulties. In this work, using glyoxal-urea (GU) resin, chitosan (CS), and soy protein isolate (SPI) as the primary raw materials in order to effectively mitigate the release of free formaldehyde commonly found in traditional wood-based panels. Obtaining an adhesive with high strength, excellent water resistance, and a stable cross-linking structure of GU/CS/SPI (CS represents different mass fractions of chitosan solution).
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