Aiming at full sustainability of CO2 separation processes, a series of supported ionic liquid membranes based on environmentally friendly cholinium carboxylate ionic liquids were successfully prepared. Their gas permeation properties were measured and high permselectivities were obtained for both CO2 /CH4 and CO2 /N2 .
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http://dx.doi.org/10.1002/cssc.201300613 | DOI Listing |
ACS Biomater Sci Eng
January 2025
National Centre for Nanoscience and Nanotechnology, University of Madras, Guindy campus, Chennai, Tamilnadu 600025, India.
Hydroxyapatite (HAP) is a well-known medically renowned bioactive material known for its excellent biocompatibility and mechanical stability, but it lacks fast bioactivity. The restricted release of ions from hydroxyapatite encourages the search for a faster bioactive material that could replicate other properties of HAP. A new sol-gel-mediated potentially bioactive glass material that could mimic the structure of HAP but can surpass the performance of HAP bioactively has been formulated in this study.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China. Electronic address:
Hydrogel-based flexible electronic devices have garnered significant attention due to their excellent mechanical properties, high electrical conductivity, and signal sensitivity. Nevertheless, internal water molecules crystallize inevitably at low temperatures, impairing the performance of hydrogels. Designing anti-freezing and tough hydrogels to meet long-term stability requirements is extremely challenging.
View Article and Find Full Text PDFJ Chromatogr A
January 2025
Faculty of Chemistry, Analytical Chemistry, University of Marburg, Hans-Meerwein-Str. 4, Marburg 35043, Germany. Electronic address:
Phosphonic acid cation exchange materials (PCX) are synthesized by atom transfer radical polymerization (ATRP) followed by alkyne-azide click-chemistry. ATRP is used to synthesize polymeric chains of diethyl 4-vinylbenzylphosphonate with different chain lengths, which are covalently bonded to the surface of monodisperse polystyrene-divinylbenzene (PS/DVB) particles by click-chemistry. The functionalized particles are characterized by FIB-SEM, IR and Schoeniger combustion followed by chromatographic experiments.
View Article and Find Full Text PDFOrg Biomol Chem
January 2025
Department of Chemistry, Rabindranath Tagore University, Hojai 782435, Assam, India.
The synthesis of triazoles plays an important role in drug discovery research. 1,2,4-triazoles are considered significant scaffolds among several bioactive heterocycles due to their extensive use in the pharmaceutical and agrochemical sectors. Consequently, the importance of the synthesis of 1,2,4-triazoles a sustainable method has increased.
View Article and Find Full Text PDFSmall
January 2025
Council of Scientific and Industrial Research-Central Salt and Marine Chemicals Research Institute (CSIR-CSMCRI), Bhavnagar, Gujarat, 364002, India.
Fluorine-free organic framework polyelectrolyte membranes showing near frictionless ionic conductivities are gaining cognitive insights. However, the co-precipitation of COFs in the membranes often brings trade-offs to commission long-life electrochemical energy storage solutions. Herein, a durable and ionically miscible dual-ion exchange membrane based on triazine organic framework (TOF) is designed for alkaline redox flow batteries (RFB).
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