A large manganese-doped polyoxotitanate nanocluster Ti28MnO38(OEt)40H2, has been synthesized solvothermally. Its structure is arranged around the four-coordinate Mn(2+) dopant atom in a Keggin-type structure. A significant reduction of the band gap relative to that of undoped polyoxotitanate clusters is observed.
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| http://dx.doi.org/10.1039/c3dt53416b | DOI Listing |
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