Methyl 1-allyl-4-hy-droxy-2,2-dioxo-1H-2λ(6),1-benzo-thia-zine-3-carboxyl-ate.

Acta Crystallogr Sect E Struct Rep Online

National University of Pharmacy, 4 Blyukhera St, Kharkiv 61168, Ukraine.

Published: October 2013

There are two independent mol-ecules in the asymmetric unit of the title compound, C13H13NO5S, in both of which the ester substituent is nearly coplanar [C-C-C-O torsion angles = 2.7 (7) and -0.8 (7)°] with the planar fragment of the bicycle due to the formation of a strong O-H⋯O intra-molecular hydrogen bond. The vinyl group at the ring N atom is approximately orthogonal to the heterocyclic mean plane [C-N-C-C torsion angles = 103.1 (6) and 98.2 (5)°]. The refinement was performed on a two-component, non-merohedrally twinned crystal [population ratio = 0.483 (3):0.517 (3).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884348PMC
http://dx.doi.org/10.1107/S1600536813028572DOI Listing

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