The unit-cell dimensions and space group of the second monoclinic polymorph of the title compound, C15H11FO, differ from those of the previously reported form [Jing (2009 ▶). Acta Cryst. E65, o2515]. The title compound shows an E conformation of the C=C bond with the 4-fluoro-phenyl group opposite to the benzoyl group. The torsion angle of between the planes of the 4-fluoro-phenyl and benzoyl groups is 10.53 (6)°. In the crystal, weak C-H⋯O and C-H⋯F inter-actions form a cross-linked packing motif, building sheets parallel to (-102).
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http://dx.doi.org/10.1107/S1600536813028079 | DOI Listing |
The present perspective accentuates the synthesis of PANI-CuFeO (PCF) nanocomposite, and photocatalytic degradation of methylene blue (MB) dye using a synthesized composite. The stable PCF is confirmed and characterized by analytical techniques, namely, fourier transform infrared (FTIR) and X-ray photoelectron (XPS) spectroscopy, X-ray diffraction (XRD), energy-dispersive X-ray (EDX), scanning electron microscopy (SEM), and vibrating sample magnetometry (VSM) analysis. The synthesized PCF nanocomposites are significantly crystalline in nature, having magnetic saturation of 10.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China.
In this study, 12 mol% ceria-stabilized tetragonal zirconia polycrystal ceramics with xNdO (where x equals 0, 0.1, 0.2, 0.
View Article and Find Full Text PDFJ Phys Chem Lett
November 2024
Faculty of Chemistry, University of Wroclaw, Joliot-Curie 14, 50-383 Wrocław, Poland.
This study investigates lead-free organic-inorganic hybrids (CNH)[BiCl] () and (CNH)[BiBr] (), focusing on their structural, dielectric, ferroelectric, and optical properties. Both compounds exhibit paraelectric () to ferroelectric () phase transitions (PTs) at 230/233 K and 228/229 K, respectively, transitioning from orthorhombic () to monoclinic (2) phases, with distorted [BiX] octahedra forming 1D chains. Quasielastic neutron scattering and solid-state H NMR studies reveal the localized motion of azetidinium cations.
View Article and Find Full Text PDFJ Phys Condens Matter
November 2024
High Pressure & Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085, India.
Efficient and better energy storage materials are of utmost technological importance to reduce energy dependence on the fossil fuels. LiMnOis one such material having potential to meet most of the requirements for energy storage. This material has been synthesized using solid state synthesis route.
View Article and Find Full Text PDFInorg Chem
November 2024
School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. China.
Hybrid organic-inorganic molecular ferroelectrics (HOIMFs) have garnered significant attention for their potential applications in nonvolatile memory and spintronic devices. However, few efforts have been devoted to the photoelectric properties of lead halide molecular ferroelectrics, despite the fact that robust ferroelectricity and flexibility are desirable for thin-film photoelectric devices. Herein, we present a novel lead halide molecular ferroelectric [CNH][PbI] () synthesized hydrothermally.
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