Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-κ(2) N,O]cobalt(III).

Acta Crystallogr Sect E Struct Rep Online

College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, People's Republic of China.

Published: October 2013

In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol-ecules are linked by pairs of weak C-H⋯Br hydrogen bonds, forming inversion dimers.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884257PMC
http://dx.doi.org/10.1107/S1600536813027591DOI Listing

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