The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclo-hexyl-ammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water mol-ecule. The cyclo-hexyl-ammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions in cis positions coordinate octa-hedrally to the central Sn(IV) atom. The cohesion of the mol-ecular entities is ensured by the formation of N-H⋯O, O-H⋯O, O-H⋯Cl and N-H⋯Cl inter-actions involving cations, anions and the lattice water mol-ecule, giving rise to a layer-like arrangement parallel to (010).
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884246 | PMC |
| http://dx.doi.org/10.1107/S1600536813026901 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Crystal structure of di-cyclo-hexyl-ammonium nitrate(V).
Acta Crystallogr E Crystallogr Commun
November 2015
Department of Chemistry, Wrocław University of Technology, 27 Wybrzeże Wyspiańskiego St., 50-370 Wrocław, Poland.
In the title mol-ecular salt, C12H24N(+)·NO3 (-), the cyclohexyl rings adopt chair conformations with the exocyclic C-N bonds in equatorial orientations. In the crystal, a bifurcated N-H⋯(O,O) hydrogen bond links the cation to the anion; the ion pairs are linked via C-H⋯O hydrogen bonds, forming layers in the ac plane.
View Article and Find Full Text PDFCrystal structure of the bis-(cyclo-hexyl-ammonium) succinate succinic acid salt adduct.
Acta Crystallogr E Crystallogr Commun
August 2015
ICMUB UMR 6302, Université de Bourgogne Franche-Comté, Faculté des Sciences, 9 avenue Alain Savary, 21000 Dijon, France.
The crystal structure of the title salt adduct, 2C6H14N(+)·C4H4O4 (2-)·C4H6O4, consists of two cyclo-hexyl-ammonium cations, one succcinate dianion and one neutral succinic acid mol-ecule. Succinate dianions and succinic acid mol-ecules are self-assembled head-to-tail through O-H⋯O hydrogen bonds and adopt a syn-syn configuration, leading to a strand-like arrangement along [101]. The cyclo-hexyl-ammonium cations have a chair conformation and act as multidentate hydrogen-bond donors linking adjacent strands through inter-molecular N-H⋯O inter-actions to both the succinate and the succinic acid components.
View Article and Find Full Text PDFCrystal structure of bis-(cyclo-hexyl-ammonium) di-phenyl-dioxalatostannate(IV).
Acta Crystallogr E Crystallogr Commun
February 2015
ICMUB UMR 6302, Université de Bourgogne, Faculté des Sciences, 9 avenue Alain Savary, 21000 Dijon, France.
Reaction of oxalic acid and di-phenyl-tin dichloride in the presence of cyclo-hexyl-amine led to the formation of the title salt, (C6H14N)2[Sn(C6H5)2(C2O4)2]. The dianion is made up from an Sn(C6H5)2 moiety cis-coordinated by two chelating oxalate anions, leading to an overall distorted octa-hedral coordination geometry of the Sn(IV) atom. The negative charges are compensated by two surrounding cyclo-hexyl-ammonium cations adopting chair conformations each.
View Article and Find Full Text PDFBis(cyclo-hexyl-ammonium) tetra-chlorido-diphenyl-stannate(IV).
Acta Crystallogr Sect E Struct Rep Online
June 2014
Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.
The title compound, (C6H14N)2[Sn(C6H5)2Cl4], contains cyclo-hexyl-ammonium cations in general positions and a stannate(IV) anion that is located on a twofold rotation axis. The Sn(IV) atom in the complex anion is surrounded by four Cl(-) ligands and two trans-phenyl groups in a distorted octa-hedral configuration. The anions are connected with the cations through N-H⋯Cl hydrogen bonds.
View Article and Find Full Text PDFBis(di-cyclo-hexyl-ammonium) sulfate dihydrate.
Acta Crystallogr Sect E Struct Rep Online
March 2014
Laboratoire de Chimie Minerale et Analytique (LACHIMIA), Departement de Chimie, Faculte des Sciences et Techniques, Universite Cheikh Anta Diop, Dakar, Senegal.
In the title dihydrate salt, 2C12H24N(+)·SO4 (2-)·2H2O, the cation possesses twofold rotational symmetry, with the N atom situated on the twofold axis. The sulfate anion has fourfold roto-inversion symmetry, with the S atom located on the -4 axis. In the crystal, the components are linked via ammonium-sulfate N-H⋯O and water-sulfate O-H⋯O hydrogen bonds, forming a three-dimensional network.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!