[Ag(70)(PW(9)O(34))(2)((t)BuC[triple bond, length as m-dash]C)(44)(H(2)O)(2)](8+): ionothermal synthesis of a silver cluster encapsulating lacunary polyoxometalate ions.

Zhan-Guo Jiang Kang Shi Yu-Mei Lin Quan-Ming Wang

Chem Commun (Camb)

State Key Lab of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, 361005, P. R. China.

Published: March 2014

A silver alkynyl cluster containing a Ag70 shell and two lacunary [PW9O34](9-) templating ions was synthesized by an ionothermal approach. Fast core-shell electronic communication between silver(i) centers and polyoxometalates was verified via cyclic voltammetry studies in [BMIm]BF4.

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http://dx.doi.org/10.1039/c3cc49290g	DOI Listing

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