AI Article Synopsis
- A Diels-Alder reaction plays a crucial role in the synthesis of communesin F, allowing for precise creation of two all-carbon quaternary stereocenters with controlled stereochemistry.
- Further reactions involving the cycloadduct are detailed, aiming to build the hexacyclic core structure vital for communesin F.
- The study highlights the effectiveness of the Diels-Alder approach in complex molecule construction.
Article Abstract
A Diels-Alder reaction is used as a key step in a synthetic study toward communesin F, in order to simultaneously introduce both of the all-carbon quaternary stereocenters with complete control of relative stereochemistry. Further manipulations of the cycloadduct, toward the hexacyclic core-structure of communesin F, are also disclosed.
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| http://dx.doi.org/10.1021/ol403516s | DOI Listing |
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