Recent progress with tailored growth and post-process sorting enables carbon nanotube (CNT) assemblies with predominantly metallic or semi-conducting concentrations. Cryogenic and microwave measurements performed here show transport dimensionality and overall order increasing with increasing metallic concentration, even in atmospheric doping conditions. By 120 GHz, the conductivity of predominantly semi-conducting assemblies grew to 400% its DC value at an increasing growth rate, while other concentrations a growth rate that tapered off. A generalized Drude model fits to the different frequency dependent behaviors and yields useful quality control parameters such as plasma frequency, mean free path, and degree of localization. As one of the first demonstrations of waveguides fabricated from this material, sorted CNTs from both as-made and post-process sources were inserted into sections of practical micro-strip. With both sources, sorted CNT micro-strip increasingly outperformed the unsorted with increasing frequency-- illustrating that sorted CNT assemblies will be important for high frequency applications.
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http://dx.doi.org/10.1038/srep03762 | DOI Listing |
Talanta
January 2024
School of Laboratory Medicine, Hubei University of Chinese Medicine, 16 Huangjia Lake West Road, Wuhan, 430065, PR China. Electronic address:
Endotoxin in the blood can cause unexplained fever, and even death due to endotoxemia and bacteremia. Rapid and sensitive detection of endotoxin has become a priority event to intervene in the occurrence of dangerous diseases in time. In this context, a carbon nanotubes-based field-effect transistor (CNTs FET) nanosensor is developed to realize the rapid, label-free and sensitive detection of endotoxin.
View Article and Find Full Text PDFAnal Chim Acta
September 2023
School of Laboratory Medicine, Hubei University of Chinese Medicine, 16 Huangjia Lake West Road, Wuhan, 430065, China. Electronic address:
Since the exosomal protein level is related to many diseases, sensitive detection of exosomal protein is highly desirable. Here, we describe a polymer-sorted high-purity semiconducting carbon nanotubes (CNTs) films-based field-effect transistor (FET) biosensor for ultrasensitive and label-free detection of MUC1, a transmembrane protein highly expressed in breast cancer exosomes. Polymer-sorted semiconducting CNTs hold advantages including high purity (>99%), high CNT concentration, and short processing time (<1 h), but they are difficult to be stably functionalized with biomolecules because of lacking hanging bonds on their surface.
View Article and Find Full Text PDFBiomolecules
January 2023
Department of Electrical and Biomedical Engineering, Fairfield University, Fairfield, CT 06834, USA.
Carbon nanotubes (CNT) have fascinating applications in flexible electronics, biosensors, and energy storage devices, and are classified as metallic or semiconducting based on their chirality. Semiconducting CNTs have been teased as a new material for building blocks in electronic devices, owing to their band gap resembling silicon. However, CNTs must be sorted into metallic and semiconducting for such applications.
View Article and Find Full Text PDFSensors (Basel)
December 2021
Laboratoire de Physique des Interfaces et des Couches Minces (LPICM), Centre National de la Recherche Scientifique (CNRS), Ecole Polytechnique, IP Paris, 91128 Palaiseau, France.
Carbon nanotubes (CNTs) combine high electrical conductivity with high surface area and chemical stability, which makes them very promising for chemical sensing. While water quality monitoring has particularly strong societal and environmental impacts, a lot of critical sensing needs remain unmet by commercial technologies. In the present review, we show across 20 water monitoring analytes and 90 references that carbon nanotube-based electrochemical sensors, chemistors and field-effect transistors (chemFET) can meet these needs.
View Article and Find Full Text PDFJ Clin Med
December 2021
Department of Rehabilitation Medicine, Kyungpook National University Chilgok Hospital, Daegu 41404, Korea.
: To determine the effectiveness of computer-assisted cognitive rehabilitation and compare the patterns of cognitive function recovery occurring in both traumatic brain injury (TBI) and stroke. A total of 62 patients were finally enrolled, consisting of 30 with TBI and 32 with stroke. The patients received 30 sessions of computer-assisted cognitive rehabilitation (Comcog) five times per week.
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