A mononuclear cobalt complex with an organic ligand acting as a precatalyst for efficient visible light-driven water oxidation.

Chem Commun (Camb)

Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China.

Published: February 2014

N,N'-Bis(salicylidene)ethylenediaminecobalt(II) (1) has been investigated as a highly efficient water oxidation precatalyst with a TON of 854 at pH = 9.0, using [Ru(bpy)3](ClO4)2 as a photosensitizer and Na2S2O8 as a sacrificial electron acceptor.

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Source
http://dx.doi.org/10.1039/c3cc48059cDOI Listing

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