6-Ferrocenoyl-7-phenyl-spiro-[hexa-hydro-pyrrolo-[1,2-c][1,3]thia-zole-5,11'-indeno-[1,2-b]quinoxaline].

Acta Crystallogr Sect E Struct Rep Online

Centre of Advanced Study in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai 600 025, India.

Published: January 2014

In the title compound, [Fe(C5H5)(C32H24N3OS)], both the thia-zolidine ring and the pyrrolidine ring adopt an envelope conformation, with the S atom and the phenyl-bearing C atom, respectively, as the flaps. The thia-zolidine ring mean plane makes a dihedral angle of 59.08 (11)° with the pyrrolidine ring mean plane, which in turn makes a dihedral angle of 83.40 (10)° with the cyclo-pentane ring, indicating that the latter two rings are almost orthogonal to one another. In the crystal, a pair of C-H⋯O hydrogen bonds link the mol-ecules forming inversion dimers. The dimers are linked via π-π inter-actions [centroid-centroid distance = 3.7764 (10) Å] involving the quinoxaline moieties forming chains propagating along [1-10].

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884422PMC
http://dx.doi.org/10.1107/S1600536813022605DOI Listing

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