A porous metal-organic framework with high surface area was designedly synthesized, in which polyhedral cages and one-dimensional channels coexist. It shows a total gravimetric H2 uptake of 11.35 wt% at 77 K and 90 bar and a total CH4 uptake of 305.07 cm(3) g(-1) at 298 K and 35 bar.
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