A dipodal fluorescent receptor, 2,2'-[ethane-1,2-diylbis(iminoethane-1,1-diyl)]diphenol (), with amine and hydroxyl moieties as binding sites has been synthesised and characterized with spectroscopic methods and single crystal X-ray techniques. The recognition of the anions with receptor was studied using UV-Vis and fluorescence spectroscopy. The (1)H-NMR spectroscopic and DFT studies revealed the distinct recognition of I(-) ions over the other surveyed anions.

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http://dx.doi.org/10.1039/c3dt52690aDOI Listing

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