Water wetting and adhesion control on polymeric patterns are achieved by tuning the configuration of their surface's structural characteristics from single to dual and triple length-scale. In particular, surfaces with combined micro-, submicrometer-,and nanoroughness are developed, using photolithographically structured SU-8 micro-pillars as substrates for the consecutive spray deposition of polytetrafluoroethylene (PTFE) submicrometer particles and hydrophobically capped iron oxide colloidal nanoparticles. The PTFE particles alone or in combination with the nanoparticles render the SU-8 micropillars superhydrophobic. The water adhesion behaviour of the sprayed pillars is more complex since they can be tuned gradually from totally adhesive to completely non adhesive. The influence of the hierarchical geometrical features of the functionalized surfaces on this behaviour is discussed within the frame of the theory. Specially designed surfaces using the described technique are presented for selective drop deposition and evaporation. This simple method for liquid adhesion control on superhydrophobic surfaces can find various applications in the field of microfluidics, sensors, biotechnology, antifouling materials, etc.
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http://dx.doi.org/10.1021/am404565a | DOI Listing |
Langmuir
January 2025
A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russia.
The results of an investigation of an impact of the structure of recently synthesized bis(trifluoromethylsulfonyl)imide mono- and dicationic ionic liquids on their properties and behavior as lubricants for slippery liquid infused superhydrophobic coatings are presented for a wide temperature range. In this study, a new approach based on monitoring the surface tension of a liquid sessile droplet on top of a coating was exploited for the analysis of the evolution of the coating properties in prolonged contact with the liquid. It was found that the continuous contact with water flow results in slippery property degradation according to two different scenarios.
View Article and Find Full Text PDFSmall
January 2025
College of Materials Science and Engineering, Zhejiang University of Technology, Hangzhou, 310014, China.
Superhydrophobic surfaces have attracted tremendous attention due to their intriguing lotus-leaf-like water-repelling phenomenon and wide applications, however, most superhydrophobic coatings are prepared with environmentally unfriendly organic solvents and suffer from poor mechanical strength. To solve these issues, waterborne recoatable superhydrophobic (WRSH) coatings are developed based on a novel self-synthesized water-soluble fluorinated acrylic polymer and hydrophobic modified silica nanoparticles. The trade-off between waterborne and superhydrophobicity is well mediated by protonation and deprotonation of the fluorinated acrylic polymer.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013 China.
Superhydrophobic surfaces have been demonstrated to exhibit excellent anti-icing effects, but they are susceptible to the loss of ice repellency as a result of external impacts. This paper proposes a novel bionic armour structure that combines an armour structure with an arrowroot bionic structure. A composite method combining laser etching and chemical modification was employed to achieve superhydrophobicity on the surface of the aluminium alloy.
View Article and Find Full Text PDFLangmuir
January 2025
School of Textile Science and Engineering, Tiangong University, Tianjin 300387, China.
Aerogels hold great potential in thermal insulation, catalytic supports, adsorption, and separation, due to their low density, high porosity, and low thermal conductivity. However, their inherent mechanical fragility and limited control functionality pose substantial challenges that hinder their practical use. In this study, a strategy is developed for the fabrication of cross-linked aramid nanofiber aerogels (cANFAs) by combining internanofiber surface cross-linking with ice-templating techniques.
View Article and Find Full Text PDFAdv Mater
January 2025
CAS Key Laboratory of Bio-inspired Materials and Interfacial Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
Shark skin features superhydrophilic and riblet-textured denticles that provide drag reduction, antifouling, and mechanical protection. The artificial riblet structures exhibit drag reduction capabilities in turbulent flow. However, the effects of the surface wettability of shark denticles and the cavity region underneath the denticle crown on drag reduction remain insufficiently explored.
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