InP core-shell nanowire pn-junctions doped with Zn and Sn have been investigated in terms of growth morphology and shell carrier concentration. The carrier concentrations were evaluated using spatially resolved Hall effect measurements and show improved homogeneity compared to previous investigations, attributed to the use of Sn as the n-type dopant. Anisotropies in the growth rate of different facets are found for different doping levels that in turn affects the migration of Sn and In on the nanowire surface. A route for increasing the In migration length to obtain a more homogeneous shell thickness is presented.
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http://dx.doi.org/10.1021/nl404039d | DOI Listing |
ACS Appl Mater Interfaces
December 2024
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China.
High-performance, environmentally friendly indium phosphide (InP)-based quantum dots (QDs) are urgently needed to meet the demands of rapidly evolving display and lighting technologies. By adopting the highly efficient and cost-effective one-pot method and utilizing aluminum isopropoxide (AIP) as the Al source, a series of Al-doped InP/(Al)ZnS QDs with emission maxima ranging from 480 to 627 nm were synthesized. The photoluminescence quantum yield (PLQY) of the blue, green, yellow, orange, and red QDs, with emission peaks at 480, 509, 560, 600, and 627 nm, reached 34%, 62%, 86%, 96%, and 85%, respectively.
View Article and Find Full Text PDFNano Lett
December 2024
Key Laboratory of Advanced Display and System Applications Education of Ministry, Shanghai University, 149 Yanchang Road, Shanghai 200072, China.
Indium phosphide (InP) quantum dots (QDs) are promising alternative heavy-metal CdSe QDs for light-emitting diode (LED) application. However, their highly reactive core surface is prone to oxidation, which reduces the photoluminescence quantum yield (PL QY) and impedes subsequent shell growth. Traditional etching methods using HF aqueous solution are problematic as water can induce reoxidation during or after etching.
View Article and Find Full Text PDFSmall Methods
December 2024
Division of Materials Science and Engineerin, Hanyang University, 222 Wangsimni-ro, Seongdong-gu, Seoul, 04763, Republic of Korea.
The formation of core-shell quantum dots (QDs) with type-I band alignment results in surface passivation, ensuring the efficient confinement of excitons for light-emitting applications. In such cases, the atomic composition at the core-shell heterojunction significantly affects the optical, and electrical properties of the QDs. However, for InP cores, shell materials are limited to compositions consisting of II-VI group elements.
View Article and Find Full Text PDFACS Nano
December 2024
University Bordeaux, CNRS, Bordeaux INP, ICMCB, UMR 5026, F-33600 Pessac, France.
This article describes an approach to making highly stable copper nanowire networks on any type of substrates. These nanostructured materials are highly sought after for, among other applications, the development of next-generation flexible electronics. Their high susceptibility to oxidation in air currently limits their use in the real world.
View Article and Find Full Text PDFInP quantum dots (QDs) have emerged as promising nanomaterials in various fields due to their exceptional optical properties. However, its wide emission linewidth limits further application. In this study, we synthesized high-quality InP/ZnSe/ZnS QDs by suppressing hole defects.
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