AI Article Synopsis
- The study examines the solvolyses of two compounds, -tolyl chlorothionoformate and -chlorophenyl chlorothionoformate, in various organic solvents that differ in nucleophilicity and ionizing power.
- Data is collected at 25.0 °C using the titration method to analyze the reaction rates.
- The results indicate the presence of both addition-elimination and unimolecular S1 mechanisms occurring simultaneously, based on the extended Grunwald-Winstein equation.
Article Abstract
The solvolyses of -tolyl chlorothionoformate and -chlorophenyl chlorothionoformate are studied in a variety of organic mixtures of widely varying nucleophilicity and ionizing power values. This solvolytic data is accumulated at 25.0 °C using the titration method. An analysis of the rate data using the extended (two-term) Grunwald-Winstein equation, and the concept of similarity of substrates based on their ratios, shows the occurrence of simultaneous side-by-side addition-elimination and unimolecular S1 mechanisms.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC3873162 | PMC |
| http://dx.doi.org/10.1155/2013/248534 | DOI Listing |
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