3D-porous anisotropic solids are fabricated by using horizontally and vertically aligned assemblies of silica rods with a length of ca. 2 μm and a diameter of 500 nm as templates. Templated materials include examples from metals, semiconductors, ceramics, and polymers, Ni, Si, HfO2, and PMMA, respectively. By varying the infilling conditions, the detailed mesoscale structure and degree of anisotropy can be controlled.
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http://dx.doi.org/10.1002/adma.201304809 | DOI Listing |
J Phys Condens Matter
December 2024
Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, Düsseldorf, 40225, GERMANY.
We study analytically the dynamics of an anisotropic particle subjected to different stochastic resetting schemes in two dimensions. The Brownian motion of shape-asymmetric particles in two dimensions results in anisotropic diffusion at short times, while the late-time transport is isotropic due to rotational diffusion. We show that the presence of orientational resetting promotes the anisotropy to late times.
View Article and Find Full Text PDFRSC Adv
December 2024
Department of Physics, Faculty of Science, Kasetsart University Bangkok 10900 Thailand
The synthesis of polymer/oligomer-stabilized metal nanostructures (MNS) opens up a wide range of possibilities, from fundamental materials science to practical applications in domains such as medicine, catalysis, sensing, and energy. Because of the versatility of this synthetic approach, it is a dynamic and ever-changing field of study. These polymers/oligomers have precise control over the nucleation and growth kinetics, allowing the production of mono-disperse MNS with well-defined properties.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
December 2024
Institute of Chemistry Chinese Academy of Sciences, Polymer Physics and Chemistry, North First Street 2, Zhongguancun, Haidian District, 100190, Beijing, CHINA.
The creation of anisotropic nanoparticles (NPs) by polymerization and/or self-assembly (SA) has significantly promoted the applications of polymer nanomaterials in many fields. However, polymer nanorods are not easily accessible via conventional polymerization or SA. Here we report a one-step route to synthesize single-domain smectic liquid crystalline (LC) nanorods utilizing oriented attachment (OA) that was usually found in the synthesis of inorganic NPs, synchronized with polymerization and SA.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2024
Institute of Physical Chemistry, Rheinisch-Westfälische Technische Hochschule Aachen University, Aachen 52074, Germany.
The adsorption of ellipsoidal colloidal particles on liquid interfaces induces interfacial deformation, resulting in anisotropic interface-mediated interactions and the formation of superstructures. Soft prolate-shaped microgels at the air-water interface offer an ideal model for studying spontaneous capillary-driven self-assembly due to their tunable aspect ratio, controlled functionality, and softness. These microgels consist of a polystyrene core surrounded by a cross-linked, fluorescently labeled poly([Formula: see text]-isopropylmethylacrylamide) shell.
View Article and Find Full Text PDFPhys Rev E
November 2024
Department of Physics, University of California Merced, Merced, California 95343, USA.
Platinum-coated Janus colloids exhibit self-propelled motion in aqueous solution via the catalytic decomposition of hydrogen peroxide. Here, we report their motion in a uniformly aligned nematic phase of lyotropic chromonic liquid crystal, disodium cromoglycate (DSCG). When active Janus colloids are placed in DSCG, we find that the anisotropy of the liquid crystal imposes a strong sense of direction to their motion; the Janus colloids tend to move parallel to the nematic director.
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