AI Article Synopsis
- - A new chemosensor using tetraphenylethene shows an increase in fluorescence by switching on in response to the binding of L-tartarate.
- - The sensor works through a cooperative binding process that allows it to form cyclic structures, which enhances fluorescence.
- - It selectively detects dicarboxylates over monocarboxylates, making it useful for early screening of metabolic disorders.
Article Abstract
A novel tetraphenylethene-based fluorescence (FL) chemosensor exhibits nonlinear turn-on FL switching though cooperative binding of L-tartarate, where its convergent binding to form cyclic substructures is responsible for the FL increase. This binding scheme achieves selective detection of dicarboxylates over monocarboxylates, thus is potentially applicable to the preliminary screening for metabolic disorders.
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| http://dx.doi.org/10.1002/chem.201304031 | DOI Listing |
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