Metal-chelation and internal H bonds have been found to greatly enhance the photoelimination quantum efficiency of B,N-heterocycles by 2 orders of magnitude. Green phosphorescent Pt(II)-functionalized 1,2-azaborines have been achieved via photoelimination. A mechanistic pathway for the PE reaction has been established.
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Chelation-assisted photoelimination of B,N-heterocycles.
Org Lett
January 2014
Department of Chemistry, Queen's University, Kingston, Ontario K7L 3N6, Canada.
Metal-chelation and internal H bonds have been found to greatly enhance the photoelimination quantum efficiency of B,N-heterocycles by 2 orders of magnitude. Green phosphorescent Pt(II)-functionalized 1,2-azaborines have been achieved via photoelimination. A mechanistic pathway for the PE reaction has been established.
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