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Reversible high-capacity Si nanocomposite anodes for lithium-ion batteries enabled by molecular layer deposition. | LitMetric

Reversible high-capacity Si nanocomposite anodes for lithium-ion batteries enabled by molecular layer deposition.

Adv Mater

Department of Mechanical Engineering, University of Colorado at Boulder, Boulder, CO, 80309, USA; National Renewable Energy Laboratory, 1617 Cole Boulevard, Golden, CO, 80401, USA.

Published: March 2014

The molecular-layer deposition of a flexible coating onto Si electrodes produces high-capacity Si nanocomposite anodes. Using a reaction cascade based on inorganic trimethylaluminum and organic glycerol precursors, conventional nano-Si electrodes undergo surface modifications, resulting in anodes that can be cycled over 100 times with capacities of nearly 900 mA h g(-1) and Coulombic efficiencies in excess of 99%.

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Source
http://dx.doi.org/10.1002/adma.201304714DOI Listing

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