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Thermal decomposition synthesis of CuO on TiO NTs as promising photocatalysts for effective photoelectrocatalytic hydrogen evolution and pollutant removal.

Environ Res

January 2025

College of Civil Engineering, Hefei University of Technology, Hefei, 238000, China; Chinaland Solar Energy Co., Ltd., Hefei, 238000, China. Electronic address:

The preparation strategy is the important factor to obtain the effective photocatalyst, and the thermal decomposition could be used to prepare photocatalysts with high crystallinity and photoactivity. In this paper, thermal decomposition method was used to deposit CuO nanoparticles on TiO nanotube arrays (TiO NTs), and the TiO NTs/CuO exhibited remarkably high visible light absorption and photoelectrocatalytic performances toward dye degradation and Cr(VI) reduction. The potential degradation pathway and toxicities of rhodamine B (RhB) dyes and intermediates were investigated.

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The current work outlines the preparation of a TiO nanotube (NT) layer electrochemically formed on the surface of a clinically-relevant titanium alloy anodisation. This NT layer was subsequently modified alternating current electrodeposition to incorporate copper micro- and nanoparticles on top of and within the NTs. Physical characterisation of the NT layer and the copper-incorporated NTs was carried out through analysis of the surface morphology, elemental composition, crystallinity, and stability SEM, EDX, XRD, and ICP-OES, respectively.

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We present a novel approach for enhancing photocatalytic efficiency by developing polyaniline (PANI) and polyindole (PIN)-coated TiO nanotubes (TNT) through a combination of chemical oxidation and hydrothermal processes. The PANI-PIN coating was systematically applied to both the internal and external surfaces of the nanotubes to enhance the photocatalytic active sites and optimize pollutant adsorption. The dual-coated structure enhances the interaction with pollutants, facilitating a more efficient degradation of 4-nitrophenol (4-NP) when exposed to visible light.

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Super hydrophilic and super oleophobic carbon nanotube/TiO composite membranes for efficient separation of algal-derived oil/water emulsions.

Colloids Surf B Biointerfaces

December 2024

Department of Chemical Technologies, Iranian Research Organization for Science and Technology (IROST), Tehran, Iran.

The separation of oil from microalgae aqueous emulsions is a critical step in producing algal-derived biofuels and nutraceuticals. This study presents the development of super hydrophilic and super oleophobic composite membranes to efficiently separate algal oil from oil/water emulsions. Carbon nanotubes (CNTs) were functionalized with polydopamine (PDA), polyethylene glycol (PEG), and titanium dioxide (TiO) nanoparticles and coated onto a mixed cellulose ester (MCE) substrate to fabricate the composite membranes.

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The current study investigates and compares the biological effects of ultrathin conformal coatings of zirconium dioxide (ZrO) and vanadium pentoxide (VO) on osteoblastic MG-63 cells grown on TiO nanotube layers (TNTs). Coatings were achieved by the atomic layer deposition (ALD) technique. TNTs with average tube diameters of 15, 30, and 100 nm were fabricated on Ti substrates (via electrochemical anodization) and were used as primary substrates for the study.

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