Kernel function-based regression models were constructed and applied to a nonlinear hydro-chemical dataset pertaining to surface water for predicting the dissolved oxygen levels. Initial features were selected using nonlinear approach. Nonlinearity in the data was tested using BDS statistics, which revealed the data with nonlinear structure. Kernel ridge regression, kernel principal component regression, kernel partial least squares regression, and support vector regression models were developed using the Gaussian kernel function and their generalization and predictive abilities were compared in terms of several statistical parameters. Model parameters were optimized using the cross-validation procedure. The proposed kernel regression methods successfully captured the nonlinear features of the original data by transforming it to a high dimensional feature space using the kernel function. Performance of all the kernel-based modeling methods used here were comparable both in terms of predictive and generalization abilities. Values of the performance criteria parameters suggested for the adequacy of the constructed models to fit the nonlinear data and their good predictive capabilities.
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http://dx.doi.org/10.1007/s10661-013-3576-6 | DOI Listing |
Environ Pollut
January 2025
Fujian Provincial Key Laboratory for Coastal Ecology and Environmental Studies, State Key Lab of Marine Environmental Science, College of the Environment and Ecology, Xiamen University, Xiamen, Fujian 361102, China. Electronic address:
A major proportion of metal contaminants in aquatic environments is bound to suspended particulate matter (SPM), yet environmental monitoring typically focuses on dissolved metals, with the filtration step removing SPM. This step may inadvertently hide the potential risks posed by particulate metals. In this study, we used stable isotope tracers to quantify the contributions of SPM-bound metals to the bioaccumulation of nickel (Ni), copper (Cu), zinc (Zn), cadmium (Cd), and lead (Pb) in Ruditapes philippinarum, a widely distributed clam crucial to global aquaculture.
View Article and Find Full Text PDFJ Environ Manage
January 2025
School of Energy & Environmental Engineering, Hebei University of Technology, Tianjin, 300401, China. Electronic address:
Photosynthetic bacteria (PSB) excel in wastewater treatment by removing pollutants and generating biomass but are challenging to optimize due to complex operational and environmental interactions. Neural Ordinary Differential Equations, Elastic Net, Stacking, and Categorical Boosting were applied as artificial intelligence methods to predict chemical oxygen demand (COD) removal efficiency, biomass productivity, biomass yield, and energy yield. Among these, the Stacking model demonstrated superior predictive performance across all targets.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Department of Geological Sciences & Engineering, Queen's University, Kingston, Ontario, Canada. Electronic address:
Thiolated arsenic (As) compounds have been identified in various natural and engineered environments worldwide and are important for the biogeochemical cycling of As, yet quantitative data regarding their stability and transformation rates remains scarce. This study investigates the oxidation kinetics of mono-, di-, and tri-thioarsenate at varying pH, Fe, and (thio-)As concentrations in the aqueous phase. Experiments conducted over four weeks revealed that all thioarsenates were oxidized faster at lower pH, with rates of up to several μmoles/L/d at a pH of 3.
View Article and Find Full Text PDFChemosphere
January 2025
Department of Civil and Environmental Engineering, University of Maryland, College Park, MD, 20742, USA. Electronic address:
Polycyclic Aromatic Hydrocarbons (PAHs) and Polychlorinated Biphenyls (PCBs) are recalcitrant organic pollutants often detected in stormwater. Various stormwater control measures (SCMs) can remove PAHs and PCBs by filtration, adsorption, and biodegradation. However, dissolved PAHs and PCBs remain present in the treated outflow of SCMs.
View Article and Find Full Text PDFJ Environ Sci (China)
July 2025
John A. Reif, Jr. Department of Civil and Environmental Engineering, New Jersey Institute of Technology, Newark, New Jersey 07102, USA.
In this study, synthetic wastewater containing 110 µg/L arsenate (As(V)), 0-20 mg/L fulvic acid (FA), and 0-12.3 mg/L phosphate was treated with 3 mg/L Fe. The mechanisms of FA and phosphate effects on As(V) removal by ferric chloride were determined using 0.
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