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Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling--synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A. | LitMetric
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Regioselective prenylation of bromocarbazoles by palladium(0)-catalysed cross coupling--synthesis of O-methylsiamenol, O-methylmicromeline and carquinostatin A.

Claudia Thomas Olga Kataeva Arndt W Schmidt Hans-Joachim Knölker

Org Biomol Chem

Department Chemie, Technische Universität Dresden, Bergstrasse 66, 01069 Dresden, Germany.

Published: February 2014

We describe the regioselective prenylation of 3-bromocarbazole by palladium(0)-catalysed cross coupling with a prenylstannane or a prenylboronate. The procedure is applied to the synthesis of precursors for biologically active carbazole alkaloids.

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http://dx.doi.org/10.1039/c3ob42297fDOI Listing

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