Bioremediation is a relatively efficient and cost-effective technology for treating polluted soils. However, the availability of suitable electron acceptors to sustain microbial respiration can reduce the microbial activity. This work aims to evaluate the impact of burying electrically conductive electron acceptors in soil for enhancing the removal of dibenzothiophene (DBT) by native electrogenic microbes. Although this novel approach is based on the use of a microbial electrochemical technology as microbial fuel cells, our goal is not to harvest energy but to maximize bioremediation, so we concluded to name the device as Microbial Electroremediating Cell (MERC). Our results proved that stimulating the microbial electrogenic metabolism, DBT removal was enhanced by more than 3-fold compared to the natural attenuation. On top of that, ecotoxicological test using green algae confirms a decrease of 50% in the toxicity of the treated soil during incubation in MERC, in contrast to the unaltered values detected under natural conditions.
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http://dx.doi.org/10.1016/j.chemosphere.2013.11.060 | DOI Listing |
Org Biomol Chem
January 2025
Advanced Catalysis and Green Manufacturing Collaborative Innovation Center, School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China.
A visible-light-promoted azidation/arylation of unactivated alkenes with Togni-N has been achieved, leading to a series of azidated pyrrolo[1,2-]indoles under photocatalyst-free conditions. Notably, an EDA complex derived from the electron-rich indole derivatives and Togni-N served as the key intermediate in this reaction.
View Article and Find Full Text PDFDalton Trans
January 2025
Department of Chemistry, Universitat de les Illes Balears, Crta de Valldemossa km 7.5, 07122 Palma de Mallorca, Baleares, Spain.
This perpective delves into the emerging field of matere bonds, a novel type of noncovalent interaction involving group 7 elements such as manganese, technetium, and rhenium. Matere bonds, a new member of the σ-hole family where metal atoms act as electron acceptors, have been shown experimentally and theoretically to play significant roles in the self-assembly and stabilization of supramolecular structures both in solid-state and solution-phase environments. This perspective article explores the physical nature of these interactions, emphasizing their directionality and structural influence in various supramolecular architectures.
View Article and Find Full Text PDFNanoscale Adv
December 2024
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang Hangkong University Nanchang 330063 P. R. China.
Photocatalytic reduction of CO to produce organic fuels is a promising strategy for addressing carbon reduction and energy scarcity. Transition metal carbides (TiCT ) are of particular interest due to their unique layered structures and excellent electrical conductivity. However, the practical application of TiCT is limited by the poor separation efficiency of photogenerated charge carriers and the low migration ability of photogenerated electrons.
View Article and Find Full Text PDFChemistry
January 2025
Shandong Normal University, Chemistry, No.88 Wenhua East Road, 250014, Jinan, CHINA.
Non-fused electron acceptors have obtained increasing curiosity in organic solar cells (OSCs) thanks to simple synthetic route and versatile chemical modification capabilities. However, non-fused acceptors with varying quinoxaline core and as-cast device have rarely been explored, and the molecular structure-photovoltaic performance relationship of such acceptors remains unclear. Herein, two non-fused acceptors L19 and L21 with thienyl substituted non-fluorinated/fluorinated quinoxaline core were developed via five-step synthesis.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Osaka University Graduate School of Engineering Science School of Engineering Science: Osaka Daigaku Daigakuin Kiso Kogaku Kenkyuka Kiso Kogakubu, Department of Materials Engineering Science, Machikaneyama 1-3, 560-8531, Toyonaka, JAPAN.
An overcrowded ethylene composed of electron-donating anion, naphthoxide, and electron-accepting cation, acridinium, has been synthesized. It is in equilibrium between a folded conformer having a smaller permanent dipole moment with visible light absorption and a twisted conformer having a larger permanent dipole moment with NIR light absorption. The overcrowded ethylene shows multiple NIR chromisms, such as solvatochromism, thermochromism, mechanochromism, vapochromism, halochromism, and amphoteric electrochromisms, which are caused by the conformational change between folded and twisted conformers or by controlling the energy difference between the HOMO of the donor moiety and the LUMO of the acceptor moiety.
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