Novel dynamic experiments have enabled the identification of a macroscopic solidlike response in the isotropic phase of a low molecular weight liquid crystal, 4,4'-n-octylcyanobiphenyl (8CB). This unknown property indicates that the low frequency shear elasticity identified in the isotropic phase of liquid crystal polymers is not reminiscent from the glass transition but reveals likely a generic property of the liquid state. The comparison to high molecular weight liquid crystals indicates, however, that the shear modulus is much enhanced when the liquid crystal moieties are attached to a polymer chain. The macroscopic length scales probed (0.050-0.100 mm) exclude wall-induced effects.
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http://dx.doi.org/10.1103/PhysRevE.88.050501 | DOI Listing |
Adv Mater
January 2025
State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, P. R. China.
Effective modifications for the buried interface between self-assembled monolayers (SAMs) and perovskites are vital for the development of efficient, stable inverted perovskite solar cells (PSCs) and their tandem photovoltaics. Herein, an ionic-liquid-SAM hybrid strategy is developed to synergistically optimize the uniformity of SAMs and the crystallization of perovskites above. Specifically, an ionic liquid of 1-butyl-3-methyl-1H-imidazol-3-iumbis((trifluoromethyl)sulfonyl)amide (BMIMTFSI) is incorporated into the SAM solution, enabling reduced surface roughness, improved wettability, and a more evenly distributed surface potential of the SAM film.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Inorganic Polymers, "Petru Poni" Institute of Macromolecular Chemistry, Aleea Gr. Ghica Voda 41A, 700487 Iasi, Romania.
The locomotion of various organisms relies on the alternated elongation-contraction of their muscles or bodies. Such biomimicry can offer a promising approach to developing soft robotic devices with improved mobility and efficiency. Most strategies to mimic such motions rely on reversible size modifications of some materials upon exposure to external stimuli.
View Article and Find Full Text PDFACS Omega
December 2024
College of Pipeline and Civil Engineering, China University of Petroleum (East China), Qingdao, Shandong 266580, People's Republic of China.
With the gradual application of enhanced oil recovery by CO (CO-EOR), the rheological behavior of produced fluid is altered due to CO dissolution and degassing. This work focuses on the composition, physical properties, gelation and yield characteristics, and viscosity-temperature properties of crude oil containing paraffinic wax after CO treatment. Special attention is given to the effect of the phase state of CO.
View Article and Find Full Text PDFHeliyon
January 2025
Division of Oral and Maxillofacial Surgery, Faculty of Dentistry, Thammasat University, Pathum Thani, 12120, Thailand.
Objectives: To evaluate the accuracy (trueness and precision) of liquid crystal display (LCD)-printed orthognathic surgical splints under two different post-processing conditions-rinsing solvent and post-polymerization time.
Materials And Methods: An LCD 3D printer was used to create 48 surgical splints using the same reference standard tessellation language (STL) files. They were randomly assigned to two experimental studies.
Heliyon
January 2025
Department of Mechanical Engineering, Sharif University of Technology, Tehran, Iran.
Lattice structures are an innovative solution to increase the strength-to-weight ratio of a structure. In this study, two polymeric hybrid lattice structures-"FRB" (a heterogenous structure which is indeed a BCC structure reinforced by FCC unit cells dispersed in a way to form a chessboard pattern in each layer) and the "Multifunctional" (a homogenous structure whose unit cells are a combination of FCC and BCC unit cells where their central nodes are connected)-are proposed, fabricated via liquid crystal display 3D printing technique, and their mechanical characteristics are evaluated under quasi-static loading, experimentally and numerically. The results indicate a 15.
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