Ruthenium-catalyzed ortho-C-H halogenations of benzamides.

Chem Commun (Camb)

Institut fuer Organische und Biomolekulare Chemie, Georg-August-Universitaet, Tammannstrasse 2, 37077 Goettingen, Germany.

Published: February 2014

[Ru3(CO)12] and AgO2C(1-Ad) enabled the first ruthenium-catalyzed intermolecular halogenations of arenes via C-H activation. Thereby, brominations and iodinations of electron-rich and electron-deficient benzamides were achieved in a highly selective fashion.

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Source
http://dx.doi.org/10.1039/c3cc47852aDOI Listing

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