Hydrogenase biomimetics: Fe2(CO)4(μ-dppf)(μ-pdt) (dppf = 1,1'-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst.

Shishir Ghosh Graeme Hogarth Nathan Hollingsworth Katherine B Holt Shariff E Kabir Ben E Sanchez

Chem Commun (Camb)

Department of Chemistry, University College London, 20 Gordon Street, London, WC1H 0AJ, UK.

Published: January 2014

Fe2(CO)4(μ-dppf)(μ-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

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http://dx.doi.org/10.1039/c3cc46456c	DOI Listing

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