Thinning and rupture of liquid films by moving slot jets.

Langmuir

Mesoscopic Transport Phenomena Group, Department of Applied Physics, Eindhoven University of Technology, Den Dolech 2, 5612AZ Eindhoven, The Netherlands.

Published: December 2013

We present systematic experiments of the rupture and dewetting of thin films of a nonvolatile polar liquid on partially wetting substrates due to a moving slot jet, which impinges at normal incidence. The relative motion was provided by a custom-built spin coater with a bidirectionally accessible axis of rotation that enabled us to measure film thickness profiles in situ as a function of substrate velocity using dual-wavelength interference microscopy. On partially wetting polymeric substrates, dry spots form in liquid films with a residual thickness well below 1 μm. We measured the density of dry spots as well as the density and size distribution of the residual droplets as a function of film thickness. In a certain parameter range, the droplet distributions exhibit pronounced anisotropy due to the effect of long-range shear stresses on the dewetting rim instability. We find robust power-law scaling relations over a large range of film thicknesses and a striking similarity to literature data obtained with ultrathin polymer melt layers on silicon substrates.

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http://dx.doi.org/10.1021/la403988nDOI Listing

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