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Synthesis of 3,4-dibenzyltetrahydrofuran lignans (9,9'-epoxylignanes). | LitMetric
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Synthesis of 3,4-dibenzyltetrahydrofuran lignans (9,9'-epoxylignanes).

Monika Pohjoispää Kristiina Wähälä

Molecules

Laboratory of Organic Chemistry, Department of Chemistry, P.O. Box 55, FIN-00014, University of Helsinki, Helsinki, 00560, Finland.

Published: October 2013

Different strategies for the racemic or enantiospecific total syntheses of plant and mammalian 3,4-dibenzyltetrahydrofuran lignans are reviewed and compared. The multi-step approaches have various key step strategies: Diels-Alder reactions, Stobbe condensations, Michael additions, alkylations, nitrile oxide cycloadditions, radical cyclisations, dianion and oxidative couplings.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270424PMC
http://dx.doi.org/10.3390/molecules181113124DOI Listing

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