Pt-Cu alloy concave nanocubes enclosed by high-index {511} facets were synthesized in high yields and exhibited substantially enhanced electrocatalytic properties for methanol oxidation relative to commercial Pt/C.
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http://dx.doi.org/10.1039/c3cc48061e | DOI Listing |
J Am Chem Soc
November 2024
Department of Chemical Engineering, Stanford University, Stanford, California 94305, United States.
Phys Chem Chem Phys
September 2024
Technische Universität Berlin, Straße des 17. Juni 124, 10623 Berlin, Germany.
Despite its well-known nobility, even platinum is subject to corrosion under the harsh conditions that many technical applications require. Based on the assumption that the platinum loss is mainly caused by the formation of volatile PtO, alloying is a promising strategy to reduce it. This investigation explores the bulk stability of Pt-Au, Pt-Ir, Pt-Re, Pt-W, Pt-Ag, Pt-Rh, Pt-Cu, Pt-Ni and Pt-Co, as well as their oxides, utilizing density functional theory, as well as and literature thermodynamic data.
View Article and Find Full Text PDFNat Commun
July 2024
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, China.
In situ exploration of the dynamic structure evolution of catalysts plays a key role in revealing reaction mechanisms and designing efficient catalysts. In this work, PtCu/MgO catalysts, synthesized via the co-impregnation method, outperforms monometallic Pt/MgO and Cu/MgO. Utilizing quasi/in-situ characterization techniques, it is discovered that there is an obvious structural evolution over PtCu/MgO from PtCuO oxide cluster to PtCu alloy with surface CuO species under different redox and CO oxidation reaction conditions.
View Article and Find Full Text PDFDalton Trans
May 2024
Department of Chemistry, School of Science, Tianjin Key Laboratory of Molecular Optoelectronic Science, Tianjin University, Tianjin 300072, China.
Direct ethanol fuel cells (DEFCs), which have been widely recognized as nontoxic and green energy conversion devices, show attractive application prospects for liquid hydrogen-carriers, due to the higher specific energy and lower toxicity of ethanol. Pt-based catalysts are widely used in DEFCs, while their poor poisoning resistance highlights the importance of composition and structure optimization. Herein, we synthesized a series of reduced graphene oxide supported ternary alloy AuPtCu/rGO ( = 0-1) catalysts with excellent ethanol oxidation performance and a composition-dependent volcano plot trend of the ordering degree was observed and rationalized.
View Article and Find Full Text PDFJ Phys Chem Lett
May 2024
Engineering Research Center of Advanced Functional Material Manufacturing of Ministry of Education, School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, PR China.
Single-atom alloy (SAA) catalysts exhibit unique and excellent catalytic properties in heterogeneous hydrogenation/dehydrogenation reactions. A thorough understanding of the microscopic surface processes is essential to improve the catalytic performance. Here, from a new perspective of the temperature-programmed desorption (TPD) spectra of hydrogen (H) on two common SAA surfaces, Pt@Cu(111) and Pd@Cu(111), we reveal and confirm the key influence of H atoms attached to Pt/Pd dopants, i.
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