One pot synthesis of cyclohexanone oxime from nitrobenzene using a bifunctional catalyst.

Chem Commun (Camb)

Instituto de Tecnología Química, Universidad Politécnica de Valencia-Consejo Superior de Investigaciones Científicas (UPV-CSIC.), Avda. De los Naranjos S/N, Valencia, Spain.

Published: February 2014

AI Article Synopsis

  • Cyclohexanone oxime is produced from nitrobenzene with a high yield of 97% in a one-step reaction.
  • The process is catalyzed by palladium and gold nanoparticles supported on carbon.
  • This reaction occurs under hydrogen at 60 °C and involves a multi-step mechanism, with intermediates and active species identified during the transformation.

Article Abstract

Cyclohexanone oxime is formed from nitrobenzene with 97% yield in a one-pot reaction catalysed by palladium and gold nanoparticles on carbon. The reaction is carried out under hydrogen at 60 °C and the overall transformation involves a multi-step catalysed mechanism from which intermediates and catalytically active species have been identified.

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Source
http://dx.doi.org/10.1039/c3cc47693fDOI Listing

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