A highly ordered nanoporous NiTi oxide layers were fabricated on Ti alloys with high Ni contents (50.6 at.%) by a combination of self-organizing anodization at 0°C and subsequent selective etching in H2O2. The key for successful formation of such layers is to sufficiently suppress the dissolve of NiO by applying lower temperature during anodization. The resulting nanoporous structure is connected and well-adhered, which exhibits a much higher electrochemical cycling stability in 0.1 M NaOH. Without further surface modification or the use of polymer binders, the layers can be behave as a low-cost, stable and sensitive platform in non-enzymatic glucose sensing.
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http://dx.doi.org/10.1038/srep03323 | DOI Listing |
Nanoscale
January 2025
Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, 16424 Depok, West Java, Indonesia.
This study reports on the development of a highly sensitive non-enzymatic electrochemical sensor based on a two-dimensional TiCT/MWCNT-OH nanocomposite for the detection of paraoxon-based pesticide. The synergistic effect between the TiCT nanosheet and the functionalized multi-walled carbon nanotubes enhanced the sensor's conductivity and catalytic activity. The nanocomposite demonstrates superior electrochemical and electroanalytical performance compared to the pristine TiCT and MWCNT-OH in detecting paraoxon-ethyl in fruit samples (green and red grapes), with a linear response range from 0.
View Article and Find Full Text PDFNanoscale
January 2025
School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China.
Due to their ease of synthesis and large specific surface area, Ni(OH) nanosheets have emerged as promising electrochemical sensing materials, attracting significant attention in recent years. Herein, a series of oxy-hydroxides based on Ni(OH) nanosheets, including NiO/Ni(OH)@NF and (MNi)O/Ni(OH)@NF (M = Co, Fe, or Cr), are successfully synthesized the electrochemical oxidation and incorporation strategies. Electrochemical tests demonstrate that these Ni(OH)-based oxy-hydroxides exhibit excellent electrochemical oxidation activity for glucose in alkaline electrolyte.
View Article and Find Full Text PDFBiosens Bioelectron
January 2025
Department of Endocrinology, Institute of Endocrine and Metabolic Diseases, The First Affiliated Hospital of USTC, Division of Life Sciences and Medicine, University of Science and Technology of China, Hefei, 230001, China; Deep Space Exploration Laboratory, University of Science and Technology of China, Hefei, 230026, China; Key Laboratory of Precision and Intelligent Chemistry/School of Chemistry and Materials Science, University of Science and Technology of China, Hefei, Anhui, 230026, China. Electronic address:
Accurate and rapid monitoring of the glucose concentration in blood is essential for the prevention and treatment of diabetes. However, existing glucose sensors still have room for improvement in terms of sensitivity, selectivity, and stability. Benefiting from the fully exposed metal sites and uniform coordination environment, single-atom catalysts (SACs) have exhibited unique electrochemical sensing performances and received extensive attention in blood glucose detection.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, Amrita School of Physical Sciences Coimbatore, Amrita Vishwa Vidyapeetham, Coimbatore, 641112, India.
J Clin Med
December 2024
Department of Pharmacology, Faculty of Medical Sciences in Zabrze, Medical University of Silesia, Jordana 38 St., 41-800 Zabrze, Poland.
Cardiovascular diseases (CVDs) are one of the most critical public health problems in the contemporary world because they are the leading cause of morbidity and mortality. Diabetes mellitus (DM) is one of the most substantial risk factors for developing CVDs. Glycated hemoglobin is a product of the non-enzymatic glycation of hemoglobin present in erythrocytes.
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